Alfa's subsidiary, Autodelta, created an evolution model called 33/2. A road version, dubbed Alfa Romeo 33 Stradale, was also introduced.
At the 24 Hours of Daytona, the Porsche 907 with 2.2L engines were dominating the overall race, but Alfa took the 2-litre class win, with Udo Schütz and Nino Vaccarella; after that the car was named as "Daytona".
Win was repeated at the Targa Florio, where Nanni Galli and Ignazio Giunti also took second place overall, followed by teammates Lucien Bianchi and Mario Casoni. Galli and Giunti then won the class at the Nürburgring 1000 km, where the 2.5L version finished for the first time, 4th place in the 3.0L class with Schütz and Bianchi. However, in most races, the Alfa drivers were outclassed by their Porsche rivals which used bigger engines.
In 1968, the car was used mainly by privateers, winning its class in the 1000km Monza, Targa Florio and Nürburgring races. At the end of season Alfa Romeo had finished third in the 1968 International Championship for Makes.